CR2330 battery.Spontaneous combustion incidents of electric vehicles occur frequently, but battery technology is not yet mature?

　　In just two months, five spontaneous combustion incidents of electric models of different brands occurred in China. When the relevant national departments issued notices asking car companies to investigate the safety hazards of electric models, we not only had some questions in our minds: Is battery technology that has been used for nearly 200 years really mature?

　　Unfortunately, this is not a definite answer: compared with the first generation of zinc-copper batteries born in the 17th century, the current battery technology has matured too much; however, if we look at large-scale industrial application and stability, Look, current battery technology still has many shortcomings.

　　Judging from the current electric vehicles that are extremely dependent on battery technology, the batteries on electric vehicles are classified into chemical batteries, and the power batteries used as energy storage devices are mainly lithium batteries.

　　Although lithium batteries have 6 different types according to different cathode materials, they are lithium titanate, lithium cobalt oxide, lithium manganate, lithium iron phosphate, and ternary materials (nickel cobalt aluminum and nickel cobalt manganese). However, in terms of energy density and safety, lithium iron phosphate and ternary materials are the best. Therefore, almost all power batteries of electric vehicles use these two batteries. However, as far as energy storage devices are concerned, these two batteries have not yet been developed. to perfection.

　　Low temperature lithium iron phosphate battery 3.2V 20A -20℃ charging, -40℃ 3C discharge capacity ≥70%

　　Lithium iron phosphate batteries are stable, but the energy density is too low

　　The positive electrode material of lithium iron phosphate battery is lithium iron phosphate, while the negative electrode material is mostly iron. In this way, lithium iron phosphate battery inherently has two major advantages. First, it is low cost and suitable for large-scale use; second, it does not contain heavy metals. , causing less environmental pollution. In addition, because the working voltage of lithium iron phosphate batteries is only 3.2V, and the P-O bond of lithium iron phosphate is relatively stable, there will be no leakage when stored at zero voltage. At the same time, it is very safe under high temperature conditions or when overcharged.

　　However, under low temperature conditions, the attenuation of lithium iron phosphate batteries is more serious, and the battery capacity often drops to 20% or even lower of the original capacity, which places great geographical restrictions on its use as a power battery for electric vehicles. In addition, due to material characteristics, lithium iron phosphate batteries are larger in size, resulting in a much lower energy density than ternary lithium batteries.

　　In other words, although lithium iron phosphate batteries have the advantages of fast charging, high cycle life (5,000 cycles of charging under experimental conditions, the remaining capacity can still maintain more than 80%), and high safety, they have low energy density and poor low-temperature performance. These two major shortcomings have become the biggest obstacles to its current large-scale commercial use.

　　Ternary lithium batteries have high energy density but poor thermal stability

　　Low temperature and high energy density 18650 3350mAh-40℃ 0.5C discharge capacity ≥60%

　　As the current main force of electric vehicle power batteries, ternary lithium batteries naturally have many advantages. First of all, in terms of applicability, ternary lithium batteries are small in size and can easily achieve high energy density, providing models with It has a long cruising range; the working voltage is generally 3.6-3.8V, and the output power is large, which can easily meet the power needs of various models. What’s more, it can maintain a relatively normal capacity in a low-temperature environment (-30°C), laying a solid foundation for large-scale use.

　　However, in terms of stability, ternary lithium batteries have obvious shortcomings. Under high temperature conditions, the ternary materials in ternary lithium batteries will decompose at 200°C, releasing oxygen atoms, which poses a great fire hazard. Several models that have caught fire recently all use ternary materials without exception. lithium battery. In addition, in terms of durability, the ternary lithium battery is far less than the 5,000 times of the lithium iron phosphate battery. After 2,000 replays, the capacity will be reduced to about 70%. Due to the expensive materials, subsequent battery replacement costs will also be one Not a small expense.

　　The advantages and disadvantages of ternary lithium batteries are very clear. When making choices, electric vehicle manufacturers have chosen its high battery life and high applicability. However, they have also spent a lot of money on developing thermal control systems to improve safety.

　　Although each has its shortcomings, they are all making progress together.

　　Although both types of batteries still have obvious shortcomings, the wave of vehicle electrification has begun to show irreversible momentum. The research and development efforts of the two batteries have also increased a lot, and some improvements have begun to be made in the shortcomings. .

　　Some lithium iron phosphate battery manufacturers have made improvements to the positive electrode, negative electrode, electrolyte and binder, allowing them to produce lithium iron phosphate batteries with a discharge efficiency of 94% at -20°C. This is This is a big improvement; in terms of energy density, some manufacturers have now made lithium iron phosphate batteries with an energy density of 190Wh/kg through material optimization and other means, although they are still quite different from Tesla's ternary lithium batteries. There is a gap, but it is not much different from mainstream lithium batteries.

　　In terms of ternary lithium batteries, the main problem is thermal stability. At present, various electric vehicle manufacturers are also actively solving the problem. Various temperature control systems such as liquid cooling and air cooling are also being introduced in more models. middle. Technically, battery manufacturers are also improving the thermal stability and durability of ternary lithium batteries by optimizing the nickel content in ternary materials.

　　Summary: At present, although battery technology is still imperfect, its progress is very rapid due to the push of vehicle electrification. In addition to these two types of batteries, the development speed of solid-state batteries and hydrogen fuel cells is also very gratifying. With the support of these technologies, the day when electric vehicles truly mature does not seem too far away from us.

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